[1]何 悦,韩季潼,吴荣第,等.氧化锌/石墨相氮化碳-聚二甲基硅氧烷改性棉织物的制备及其性能研究[J].服装学报,2025,10(06):478-484.
　HE Yue,HAN Jitong,WU Rongdi,et al.Research on the Preparation and Properties of ZnO/g-C3N4-PDMS Modified Cotton Fabric[J].Journal of Clothing Research,2025,10(06):478-484.
点击复制

氧化锌/石墨相氮化碳-聚二甲基硅氧烷改性棉织物的制备及其性能研究()

《服装学报》[ISSN:2096-1928/CN:32-1864/TS]

卷:
第10卷
期数:
2025年06期
页码:
478-484
栏目:
服装材料
出版日期:
2025-12-30

文章信息/Info

Title:
Research on the Preparation and Properties of ZnO/g-C3N4-PDMS Modified Cotton Fabric
作者:
何 悦1; 2;  韩季潼1;  吴荣第1;  蒋琦雯1;  张春明*1
1.青岛大学 纺织服装学院,山东 青岛 266071; 2.东华大学 服装与艺术设计学院,上海 200051
Author(s):
HE Yue1; 2;  HAN Jitong1;  WU Rongdi1;  JIANG Qiwen1;  ZHANG Chunming*1
1. College of Textiles and Clothing,Qingdao University,Qingdao 266071,China; 2. College of Fashion and Design,Donghua University,Shanghai 200051,China
分类号:
TS 195.5
文献标志码:
A
摘要:
针对纺织品易吸附污渍且易滋生细菌的问题,采用超声辅助混合策略制备氧化锌(ZnO)/石墨相氮化碳(g-C3N4)协同复合体系,并结合聚二甲基硅氧烷(PDMS)在棉织物表面构建微纳米粗糙结构,从光催化活性、表面润湿性及材料耐久性等方面对改性棉织物的性能进行梳理、分析。结果显示,所制ZnO/g-C3N4-PDMS改性棉织物对金黄色葡萄球菌与大肠杆菌均表现出优异的抗菌活性,在可见光照射下对亚甲基蓝的光催化降解率可达98%; 同时表现出优异的超疏水性能和良好的透气性、耐久性。研究表明,该改性棉织物兼具光催化降解、自清洁和抗菌功能,在智能纺织品、环境净化与医疗防护领域展现出广阔的应用前景。
Abstract:
To address the issues of textiles being prone to stain adhesion and bacterial growth, an ultrasonic-assisted hybrid strategy was employed to prepare a synergistic ZnO/g-C3N4 composite system. This system was combined with polydime-thylsiloxane(PDMS)to construct a micro-nano rough structure on the cotton fabric surface. The performance of the composite cotton fabric was systematically reviewed and analyzed from the aspects of photocatalytic activity, surface wettability, and material durability. The results show that the prepared ZnO/g-C3N4-PDMS modified cotton fabric exhibits excellent antibacterial activity against both Staphylococcus aureus and Escherichia coli, and achieves a photocatalytic degradation rate of up to 98% for methylene blue under visible light irradiation. Simultaneously, it demonstrates outstanding superhydrophobicity, good breathability, and durability. The research indicates that this composite textile integrates photocatalytic degradation, self-cleaning, and antibacterial functions, presenting broad application prospects in the fields of smart textiles and medical protection.

参考文献/References:

[1] 旋湘桃, 张辉, 车秋凌, 等. 自清洁织物的研究进展[J]. 纺织学报, 2025, 46(1): 227-237.
XUAN Xiangtao, ZHANG Hui, CHE Qiuling, et al. Research progress in self-cleaning fabrics[J]. Journal of Textile Research, 2025, 46(1): 227-237.(in Chinese)
[2] ZHANG M L, JIANG S, HAN F Y, et al. Recyclable, superhydrophobic and effective Ag/TiO2@PDMS coated cotton fabric with visible-light photocatalyst for efficient water purification[J]. Cellulose, 2022, 29(6): 3529-3544.
[3] 蓝丽莹, 仇巧华. 基于ZIF-L的抗菌和自清洁棉织物的制备及性能[J]. 现代纺织技术, 2025, 33(3): 48-57.
LAN Liying, QIU Qiaohua. Preparation and properties of antibacterial and self-cleaning cotton fabrics based on ZIF-L[J]. Advanced Textile Technology, 2025, 33(3): 48-57.(in Chinese)r/>[4] MENG L, SUN X X, WANG X H. A facial method for constructing superhydrophobic surface by one-step surface etching combined with melt blowing process[J]. Chemical Engineering Journal, 2024, 491: 151941.
[5] YU M Q, LYU W, LIAO Y Z, et al. Snakeskin-inspired hierar-chical winkled surface for ultradurable superamphiphobic fabrics via short-fluorinated polymer reactive infusion[J]. Advanced Fiber Materials, 2023, 5(2): 543-553.
[6] WANG B P, LI Z X, WANG Y P, et al. Eco-friendly dyeing of cotton fabrics with microbial pigments: Anionic modification for superior color, antibacterial, hydrophobic and UV protection properties[J]. Industrial Crops and Products, 2025, 223: 120276.
[7]GAO C, CHEN Y, WANG Q, et al. Multifunctional fabrics embedded with polypyrrole-silver/silver chloride nanocomposites for solar-driven steam generation and photocatalytic decontamination[J]. Separation and Purification Technology, 2023, 323: 124477.
[8] 叶远丽, 李飞, 冯志忠, 等. 纺织品抗菌整理研究进展[J]. 服装学报, 2018, 3(1): 1-8.
YE Yuanli, LI Fei, FENG Zhizhong, et al. Research progress in antibacterial finishing of textiles[J]. Journal of Clothing Research, 2018, 3(1): 1-8.(in Chinese)
[9] 刘建春, 张弛, 王佳怡, 等. SF-AgNPs/PVDF-HFP亲疏水双层电纺纤维膜的制备及其过滤抗菌性能[J]. 丝绸, 2023, 60(7): 17-25.
LIU Jianchun, ZHANG Chi, WANG Jiayi, et al. Preparation of SF-AgNPs/PVDF-HFP hydrophilic-hydrophobic bilayer electrospun fiber membranes and their filtration and antibacterial properties[J]. Journal of Silk, 2023, 60(7): 17-25.(in Chinese)
[10] 曹聪聪, 汤龙世, 刘元军, 等. 无机抗菌织物的研究进展[J]. 纺织学报, 2022, 43(11): 203-211.
CAO Congcong, TANG Longshi, LIU Yuanjun, et al. Research progress of inorganic antibacterial fabrics[J]. Journal of Textile Research, 2022, 43(11): 203-211.(in Chinese)
[11]?中华人民共和国国家质量监督检验检疫总局, 中国国家标准化管理委员会. 纺织品抗菌性能的评价 第3部分: 振荡法: GB/T 20944.3—2008[S]. 北京: 中国标准出版社, 2008.
[12] Colorfastness to laundering: accelerated: AATCC TM61—2010[S]. South Carolina: American Association of Textile Chemists and Colorists, 2010.
[13] CHENG H, WANG N N, YANG Y Q, et al. The enhanced visible light driven photocatalytic activity of zinc porphyrin/g-C3N4 nanosheet for efficient bacterial infected wound healing[J]. Journal of Colloid and Interface Science, 2023, 643: 183-195.
[14] 中华人民共和国国家质量监督检验检疫总局,中国国家标准化管理委员会. 纳米技术处理服装: GB/T 22925—2009[S]. 北京: 中国标准出版社, 2009.
[15] 陈海燕, 胡海平, 甘建昌, 等. 纳米ZnO可见光催化活性的改善及其降解性能[J]. 功能材料, 2021, 52(4): 4192-4200.
CHEN Haiyan, HU Haiping, GAN Jianchang, et al. Improvement of visible light photocatalytic activity of nano ZnO and its perfor-mance for organic pollutants degradation[J]. Journal of Functional Materials, 2021, 52(4): 4192- 4200.(in Chinese)
[16] JIANG Q W, TANG P C, CHEN W C, et al. Fabrication and characterization of a novel superhydrophobic cotton fabric with integrated 3D graphene-Ag/TiO2 aerogel for superior antibacterial performance, oil-water separation, and enhanced durability[J]. Industrial Crops and Products, 2024, 222: 119882.
[17] DONG M D, LI Q L, XIAO F J, et al. Remarkably enhanced light and ultrasonic-boosting peroxidase-like activity of g-C3N4-Cu-TCPP for antimicrobial applications[J]. Applied Surface Science, 2023, 633: 157537.
[18] LI N, TIAN Y, ZHAO J H, et al. Z-scheme 2D/3D g-C3N4@ZnO with enhanced photocatalytic activity for cephalexin oxidation under solar light[J]. Chemical Engineering Journal, 2018, 352: 412- 422.(责任编辑:沈天琦)

相似文献/References:

[1]叶远丽,李 飞,冯志忠,等.基于个人防护的棉织物吸湿快干整理[J].服装学报,2017,2(06):483.
　YE Yuanli,LI Fei,FENG Zhizhong,et al.Moisture Absorption and Fast Drying Finishing of Cotton Fabric[J].Journal of Clothing Research,2017,2(06):483.
[2]李晓强,孙 倩,秦晓雨,等.具有防水性能的PVDF/CoCl2/Cotton湿敏材料[J].服装学报,2020,5(03):195.
　LI Xiaoqiang,SUN Qian,QIN Xiaoyu,et al.PVDF/CoCl2/ Cotton Humidity Sensing Material with Waterproof Property[J].Journal of Clothing Research,2020,5(06):195.
[3]马梓星,王迎坤,林裕凯,等.银杏叶染料的提取及其在棉织物染色中的应用[J].服装学报,2025,10(02):95.
　MA Zixing,WANG Yingkun,LIN Yukai,et al.Extraction of Ginkgo Leaf Dye and Its Application in Cotton Fabric Dyeing[J].Journal of Clothing Research,2025,10(06):95.

更新日期/Last Update: 2025-12-30