[1]李晓强,孙 倩,秦晓雨,等.基于聚苯胺/聚丙烯腈纳米纤维膜的柔性空气电池阴极[J].服装学报,2020,5(02):95-100.
　LI Xiaoqiang,SUN Qian,QIN Xiaoyu,et al.Polyaniline/Polyacrylonitrile Nanofibrous Membrane Based Flexible Air-Battery Cathode[J].Journal of Clothing Research,2020,5(02):95-100.
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基于聚苯胺/聚丙烯腈纳米纤维膜的柔性空气电池阴极()
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《服装学报》[ISSN:2096-1928/CN:32-1864/TS]

卷:
第5卷
期数:
2020年02期
页码:
95-100
栏目:
服装材料科学
出版日期:
2020-04-30

文章信息/Info

Title:
Polyaniline/Polyacrylonitrile Nanofibrous Membrane Based Flexible Air-Battery Cathode
作者:
李晓强1; 2;  孙 倩1;  秦晓雨1;  王 辉1;  王烨晨1;  李大伟1;  高德康2
1.江南大学 纺织科学与工程学院,江苏 无锡 214122; 2.波司登国际控股有限公司,江苏 常熟 215532
Author(s):
LI Xiaoqiang1; 2;  SUN Qian1;  QIN Xiaoyu1;  WANG Hui1;  WANG Yechen1;  LI Dawei1;  GAO Dekang2
1.College of Textile Science and Engineering,Jiangnan University,Wuxi 214122,China; 2.Bosideng International Holding Co.,Ltd.,Changshu 215532,China
分类号:
TM 911.41; TQ 342
文献标志码:
A
摘要:
采用静电纺丝技术制备聚丙烯腈(PAN)纳米纤维膜,并在其表面原位合成聚苯胺(PANI),制备PANI/PAN纳米纤维膜; 采用扫描电子显微镜、傅里叶红外光谱仪、四探针电阻仪、热重分析仪,以及X射线衍射仪对制备的PANI/PAN纳米纤维膜进行一系列物理化学性能测试。以浸有KCl溶液的水性薄膜为电解质层,将PANI/PAN纳米纤维膜与锌金属片组装成柔性空气电池,并对其进行放电性能测定。该空气电池在2 000 s内放电电流大于0.5 mA,电压大于0.4 V。
Abstract:
Polyacrylonitrile(PAN)nanofibrous membrane was prepared with the method of electrospinning,followed by in-situ polymerization of polyaniline(PANI)on the surface of PAN nanofibers to obtain the PANI/PAN nanofibrous membrane.Scanning electron microscope(SEM),Fourier infrared spectrometer(FTIR),four-probe resistor,thermogravimetric analyzer(TG),and X-ray diffraction(XRD)were used to investigate the physicochemical properties of the prepared PANI/PAN nanofibrous membrane.In addition,a flexible air battery was assembled using PANI/PAN nanofibrous membrane and zinc sheet with water-based film immersed in KCl solution as electrolyte layer.The discharge performances were measured.The air battery discharge current and voltage within 2 000 s are higher than 0.5 mA and 0.4 V,respectively.

参考文献/References:

[1] 王春芳,王之顺,李洪飞,等.科技与时尚的结合——柔性可穿戴电池[J].化学教育,2018,39(20): 5-10.
WANG Chunfang,WANG Zhishun,LI Hongfei,et al.Combination of technology and fashion: flexible and wearable batteries[J].Chinese Journal of Chemical Education,2018,39(20): 5-10.(in Chinese)
[2] 李晓强,张家琳,王纪冬,等.湿法纺丝技术制备纤维状空气电池阳极及其性能[J].服装学报,2019,4(4): 283-287.
LI Xiaoqiang,ZHANG Jialin,WANG Jidong,et al.Preparation and performance research of fibrous zinc-air battery anode from wet-spinning[J].Journal of Clothing Research,2019,4(4): 283-287.(in Chinese)
[3] 史菁菁,郭星,陈人杰,等.柔性电池的最新研究进展[J].化学进展,2016,28(4): 577-588.
SHI Jingjing,GUO Xing,CHEN Renjie,et al.Recent progress in flexible battery[J].Progress in Chemistry,2016,28(4): 577-588.(in Chinese)
[4] 张德立,喻进华,田厚宽.静电纺丝聚合物纳米纤维力学性能表征及凝聚态结构研究进展[J].现代纺织技术,2019,27(3):10-15.
ZHANG Deli,YU Jinhua,TIAN Houkuan.A review on mechanical properties of electrospun polymer nanofibers:characterization and condensed structure[J]. Advanced Textile Technology,2019,27(3):10-15.(in Chinese)
[5] 赵晓明,孙嘉瑞.导电聚苯胺的研究进展及其在纺织领域的应用[J].纺织科学与工程学报,2018,35(1): 153-158.
ZHAO Xiaoming,SUN Jiarui.Research progress of conductive polyaniline and its application in textile field[J].Journal of Textile Science and Engineering,2018,35(1): 153-158.(in Chinese)
[6] 闾兴圣,王庚超.聚苯胺/聚合物导电材料研究进展[J].功能高分子学报,2003,16(1): 107-112.
YAN Xingsheng,WANG Gengchao.New progress of the conductive PANI/polymer composites[J].Journal of Functional Polymers,2003,16(1): 107-112.(in Chinese)
[7] 牛传文.聚苯胺复合纳米材料的制备及应用[D].上海:东华大学,2017: 11-15.
[8] 李福顺.PA6/PANI纳米纤维膜制备技术与性能研究[D].青岛:青岛大学,2017: 15-18.
[9] 王玉姣,田明伟,曲丽君.柔性智能聚苯胺/聚氨酯导电纳米纤维的制备及性能[J].高分子材料科学与工程,2016,32(4): 137-141,147.
WANG Yujiao,TIAN Mingwei,QU Lijun.Flexible and intelligent polyaniline/polyurethane composite nanofibers with conductive properties[J].Polymer Materials Science and Engineering,2016,32(4): 137-141,147.(in Chinese)
(责任编辑:邢宝妹)

相似文献/References:

[1]李晓强,张家琳,王纪冬,等.湿法纺丝技术制备纤维状锌空气电池阳极及其性能[J].服装学报,2019,4(04):283.
　LI Xiaoqiang,ZHANG Jialin,WANG Jidong,et al.Preparation and Performance Research of Fibrous Zinc-Air Battery Anode from Wet-Spinning[J].Journal of Clothing Research,2019,4(02):283.

更新日期/Last Update: 2020-04-29